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Wiley, Angewandte Chemie International Edition, 4(47), p. 746-749, 2008
Wiley, Angewandte Chemie, 4(120), p. 758-761, 2008
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Aqueous-Phase Fischer–Tropsch Synthesis with a Ruthenium Nanocluster Catalyst
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Abstract
No need for support: An aqueous-phase Fischer–Tropsch synthesis with a high turnover frequency of 12.9 h−1 has been realized over a ruthenium nanocluster catalyst (with particle diameter of 2.0 nm) at 150 °C. This catalyst, in the absence of any support, achieves an activity that exceeds those of conventional supported catalysts.