Building activities generate coarse (PM10 ≤10 µm), fine (PM2.5 ≤2.5 µm) and ultrafine particles (<100 nm) making it necessary to understand both the exposure levels of operatives on site and the dispersion of ultrafine particles into the surrounding environment. This study investigates the release of particulate matter, including ultrafine particles, during the mixing of fresh concrete (incorporating Portland cement with Ground Granulated Blastfurnace Slag, GGBS or Pulverised Fuel Ash, PFA) and the subsequent drilling and cutting of hardened concrete. Particles were measured in the 5-10,000 nm size range using a GRIMM particle spectrometer and a fast response differential mobility spectrometer (DMS50). The mass concentrations of PM2.5-10 fraction contributed ~52-64% of total mass released. The ultrafine particles dominated the total particle number concentrations (PNCs); being 74, 82, 95 and 97% for mixing with GGBS, mixing with PFA, drilling and cutting, respectively. Peak values measured during the drilling and cutting activities were 4 and 14 times the background. Equivalent emission factors were calculated and the total respiratory deposition dose rates for PNCs for drilling and cutting were 32.97±9.41 ×108 min−1 and 88.25±58.82×108 min−1. These are a step towards establishing number and mass emission inventories for particle exposure during construction activities.