Published in
American Chemical Society, Organometallics, 3(22), p. 541-547, 2003
DOI: 10.1021/om020764i
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Novel Chiral and Achiral NCN Pincer Complexes Based on 1,3-Bis(1H-1,2,4-triazol-1-ylmethyl)benzene
Journal article published in 2003 by
Enrique Díez-Barra,
Javier Guerra,
Isabel López-Solera,
Sonia Merino,
Julián Rodríguez-López 
,
Prado Sánchez-Verdú,
Juan Tejeda
,
Prado Sánchez-Verdú,
Juan Tejeda
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Abstract
NCN pincer ligands based on 1,2,4-triazole and their corresponding palladium(II) complexes have been synthesized by the reaction of 1,3-bis(1H-1,2,4-triazol-1-ylmethyl)benzene derivatives with palladium(II) acetate. All compounds are ortho,ortho-metalated. Chiral complexes were obtained by using pincer ligands with substituents on the arms. The chiral complexes are conformationally rigid up to 150 °C.