Published in
American Chemical Society, Journal of the American Chemical Society, 43(135), p. 16006-16009, 2013
DOI: 10.1021/ja407654n
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Cation-Dependent Magnetic Ordering and Room-Temperature Bistability in Azido-Bridged Perovskite-Type Compounds
Journal article published in 2013 by
Xin-Hua Zhao,
Shao-Liang Zhang,
Dong Shao 
,
Xing-Cai Huang ,
Hai-Yan Wei,
Xin-Yi Wang
,
Xing-Cai Huang ,
Hai-Yan Wei,
Xin-Yi Wang
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Abstract
A series of end-to-end azido-bridged perovskite-type compounds [(CH3)nNH4-n][Mn(N3)3] (n = 1-4) were synthesized and characterized. Structural phase transitions indicating the general lattice flexibility were observed and confirmed by the crystal structures of different phases. These materials show cation-dependent magnetic ordering at up to 92 K and magnetic bistability near room temperature.