American Chemical Society, ACS Applied Materials and Interfaces, 7(7), p. 4048-4055, 2015
DOI: 10.1021/am507744y
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Electrocatalysts for the oxygen reduction and evolution reactions (ORR/OER) are often functionally separated, meaning that they are only proficient at one of the tasks. Here we report a high-performance bi-functional catalyst for both ORR and OER in both alkaline and neutral media, which is made of cobalt-embedded nitrogen doped carbon nanotubes. In OER, it shows an overpotential of 200 mV in 0.1 M KOH and 300 mV in neutral media, while the current density reaches 50 mA cm-2 in alkaline media and 10 mA cm-2 in neutral media at overpotential of 300 mV. In ORR, it is on par with Pt/C in both alkaline and neutral media in terms of overpotential but its stability is superior. Further study demonstrated that the high performance can be contributed to the coordination of N to Co and the concomitant structural defects arising from the transformation of cobalt-phthalocyanine precursor.