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The Journal of Physical Chemistry, 21(94), p. 8334-8338

DOI: 10.1021/j100384a062

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Small-angle X-ray scattering study of fluctuations in 1-propanol-water and 2-propanol-water systems

Journal article published in 1990 by Hisashi Hayashi ORCID, Keiko Nishikawa, Takao Iijima
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Small-angle x-ray scattering (SAXS) measurements have been carried out on the 1-propanol (NPA)-water system and on the 2-propanol (IPA)-water system at 20{degree}C. In the NPA-water system, the zero angle intensity, the concentration fluctuation, the Kirkwood-Buff parameters, and Debye's correlation lengths have been determined at various concentrations. In the IPA-water system, the zero angle intensity and Debye's correlation lengths have also been determined. In both the NPA-water and IPA-water systems, all obtained parameters have maxima at about 0.2 of the mole fraction of alcohol. In terms of these parameters, the mixing state of the NPA-water and IPA-water systems is discussed and compared with that of the TBA-water system.