Formation of a Metalloporphyrin-Based Nanoreactor by Postsynthetic Metal-Ion Exchange of a Polyhedral-Cage Containing a Metal-Metalloporphyrin Framework
Journal article published in 2013 by
Xi-Sen Wang,
Matthew Chrzanowski,
Lukasz Wojtas,
Yu-Sheng Chen,
Shengqian Ma 
This paper is made freely available by the publisher.
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Abstract
A change for the better: Exchange of Cd(II) in the catalytically inactive framework MMPF-5 with Co(II) afforded a metalloporphyrin-based nanoreactor, MMPF-5(Co). This framework, consisting of small cubicuboctahedral cages, demonstrated interesting performances in the catalytic epoxidation of trans-stilbene with tBuOOH.