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Wiley, Angewandte Chemie International Edition, 38(47), p. 7263-7266, 2008

DOI: 10.1002/anie.200802087

Wiley, Angewandte Chemie, 38(120), p. 7373-7376, 2008

DOI: 10.1002/ange.200802087

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Enhancing H2Uptake by “Close-Packing” Alignment of Open Copper Sites in Metal-Organic Frameworks

Journal article published in 2008 by Xi-Sen Wang, Shengqian Ma ORCID, Paul M. Forster, Daqiang Yuan, Juergen Eckert, Joseph J. López, Brandon J. Murphy, John B. Parise, Hong-Cai Zhou
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This paper is available in a repository.

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Abstract

Inspired by close-packing of spheres, to strengthen the framework-H{sub 2} interaction in MOFs (metal-organic frameworks), a strategy is devised to increase the number of nearest neighboring open metal sites ofe ach H{sub 2}-hosting cage, and to align the open metal sites toward the H{sub 2} molecules. Two MOF polymorphs were made, one exhibiting a record high hydrogen uptake of 3.0 wt% at 1 bar and 77 k.