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American Chemical Society, Journal of Organic Chemistry, 2(80), p. 1279-1283, 2015

DOI: 10.1021/jo502611x

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Metal-Catalyzed Thermal Reactions of Cyclic β-Dicarbonyl Phenyliodonium Ylide with Styrenes

Journal article published in 2015 by Alexandra-Eleni Bosnidou ORCID, Dimitra Kalpogiannaki, Sofia Karanestora, John A. Nixas, Lazaros P. Hadjiarapoglou
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A cyclic beta-dicarbonyl phenyliodonium ylide reacted with various substituted styrenes under Rh2(OAc)4 catalysis to give cyclopropanes and dihydrofurans in a highly regioselective fashion. When styrenes with electron donating substituents or disubstituted were employed, only dihydrofurans were isolated instead. A mechanism involving two competing pathways rationalizes the results.