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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 10(70), p. m351-m351, 2014

DOI: 10.1107/s1600536814020066

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Crystal structure of bromidobis(naphthalen-1-yl)antimony(III)

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, [SbBr(C10H7)2], the SbIIIatom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intramolecular C—H...Br hydrogen bond forms anS(5) ring motif. In the crystal, weak C—H...Br interactions link the molecules into helical chains along theb-axis direction.