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Springer Verlag, Structural Chemistry, 5(16), p. 485-490

DOI: 10.1007/s11224-005-4467-4

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The Unusual Transformation of an Aromatic 1H-Imidazole into a Non-Aromatic 2H-Imidazole

Journal article published in 2005 by Antonio De La Hoz, Antonio de la Hoz ORCID, Ana Sánchez-Migallón ORCID, María Del, María del Carmen Mateo, Pilar Prieto, Lourdes Infantes ORCID, José Elguero
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Abstract

2H-Imidazole derivative 5 has been synthesized and characterized by the X-ray diffraction (XRD) method. The compound crystallizes in the monoclinic space group Cc with cell parameters a = 19.398(1), b = 8.890(1), c = 10.247(1), β = 110.76(1), Z = 4. The molecules are inter-linked through C–H· · ·O and C–H· · ·π interactions forming infinite chains.