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Elsevier, Journal of Organometallic Chemistry, 1-2(465), p. 263-265

DOI: 10.1016/0022-328x(94)87064-0

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Heterometallic sulfido clusters by metal exchange: syntheses and X-ray crystal structures of (η5-C5H4CH3)MoFeCo(CO)8(μ3-S) and (η5-C5H4CH3)2Mo2Fe(CO)7(μ3-S)

Journal article published in 1994 by Wen-Hua Sun ORCID, Shi-Yan Yang, Han-Qing Wang, Quan-Fu Zhou, Kai-Bei Yu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Heterometallic sulfido clusters (η5-C5H4CH3)MoFeCo(CO)8(μ3-S) and (η5-C5H4CH3)2Mo2Fe(CO)7(μ3-S) were obtained through metal exchange with electrophilic addition-elimination via substitution from the reaction of HFe2Co(CO)9(μ3-S) with (η5-C5H4CH3)Mo(CO)3Cl in THF. The title clusters were characterized by elemental analyses, and IR and NMR spectroscopies. The X-ray crystal structures of the title clusters are reported here as well.