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Elsevier, Journal of Quantitative Spectroscopy and Radiative Transfer, 3(97), p. 317-331

DOI: 10.1016/j.jqsrt.2005.04.015

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Line-by-line calculations of thermal infrared radiation representative for global condition: CFC-12 as an example

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This paper is available in a repository.

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Abstract

We estimate a current direct radiative forcing due to CFC-12 of 0.18 Wm(-2), which is likely to be the peak radiative forcing for CFC-12. Global measurements of CFC-12 show at present an almost negligible trend for CFC-12 and measurement in an industrialized region show evidence that the peak concentration is reached. It is expected that concentration of CFC-12 in industrialized regions begins to decline 1-3 years before the global concentration. Our radiative forcing calculations are based on a line-by-line model appropriate for simulation of global mean radiative forcing, including clouds and stratospheric temperature adjustment. The radiative forcing of 0.33 Wm(-2)/ppbv is close to earlier published results for this compound. New spectroscopic measurements for CFC-12 are performed and compared to previously published results. (C) 2005 Elsevier Ltd. All rights reserved.