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American Chemical Society, Journal of the American Chemical Society, 42(136), p. 14654-14657, 2014

DOI: 10.1021/ja506978c

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Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity

Journal article published in 2014 by Maximilian Joost, Abdallah Zeineddine, Laura Estévez ORCID, Sonia Mallet-Ladeira, Karinne Miqueu, Abderrahmane Amgoune ORCID, Didier Bourissou
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This paper is available in a repository.

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Abstract

Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild conditions and is general. The ensuing aryl gold(III) complexes have been characterized by spectroscopic and crystallographic means. DFT calculations indicate that the bending induced by the diphosphine ligand plays a key role in this process.