American Chemical Society, ACS Sustainable Chemistry and Engineering, 12(1), p. 1572-1579, 2013
DOI: 10.1021/sc4002092
Full text: Download
The sol–gel microencapsulation of free-radical initiator benzoyl peroxide in sol–gel methyl-modified silica microcapsules of core/shell geometry allows curing of acrylate-based polyurethane and polyester resin formulations sprayed from a pressurized can without the need to compartmentalize reactants from the initiator to cross-link. These results open the route to widespread application of sol–gel microcapsules to efficiently cure polymer and composite mixtures that are widely used as functional coatings, molding compounds, adhesives, and sealants.