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Wiley, Angewandte Chemie International Edition, 7(44), p. 1115-1118, 2005

DOI: 10.1002/anie.200462043

Wiley, Angewandte Chemie, 7(117), p. 1139-1142

DOI: 10.1002/ange.200462043

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The Role of Gold in Gold-Titania Epoxidation Catalysts

Journal article published in 2005 by T. Alexander Nijhuis ORCID, Tom Visser, Bert M. Weckhuysen
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This paper is available in a repository.

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Abstract

Gold can activate propane or influence titania such that a reaction occurs in which bidentate propoxy species are formed on the catalyst (see picture). In the absence of gold this reaction is not possible. This observation brings the understanding of this unique catalyst system one step further.