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American Physical Society, Physical review B, 11(79)

DOI: 10.1103/physrevb.79.113201

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Origin of magnetic moments in defectiveTiO2single crystals

Journal article published in 2009 by Shengqiang Zhou, E. Čižmár, K. Potzger, M. Krause ORCID, G. Talut, M. Helm ORCID, J. Fassbender ORCID, S. A. Zvyagin ORCID, J. Wosnitza, H. Schmidt
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This paper is available in a repository.

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Abstract

In this Brief Report we show that ferromagnetism can be induced in pure TiO2 single crystals by oxygen ion irradiation. By combining x-ray diffraction, Raman scattering, and electron-spin resonance spectroscopy, a defect complex, i.e., Ti3+ ions on the substitutional sites accompanied by oxygen vacancies, has been identified in irradiated TiO2. This kind of defect complex results in a local (TiO6−x) stretching Raman mode. We elucidate that Ti3+ ions with one unpaired 3d electron provide the local magnetic moments.