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American Chemical Society, Organic Letters, 2(14), p. 592-595, 2012

DOI: 10.1021/ol2032043

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Photoassisted “Gate-Lock” Fluorescence “Turn-on” in a New Schiff Base and Coordination Ability of E–Z Isomers

Journal article published in 2012 by Rampal Pandey, Rakesh Kumar Gupta, Pei-Zhou Li, Qiang Xu ORCID, Arvind Misra, Daya Shankar Pandey
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Rapid photoresponse (1.0-8.0 min) through fluorescence "turn-on" signaling displayed by a novel Schiff base (L) creating "gate lock" via intramolecular C-H···N interaction in photoisomerized product (L') has been described. Coordination chemistry of pre- and postirradiated species demonstrated a drastic change in the reactivity which has been supported by NMR, HRMS, UV-vis, emission, electrochemical, and complexation studies.