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Angewandte Chemie International Edition in English, 19(34), p. 2132-2134

DOI: 10.1002/anie.199521321

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Strong Binding of Paraquat and Polymeric Paraquat Derivatives by Basket-Shaped Hosts

Journal article published in 1995 by Albertus P. H. J. Schenning, Bas de Bruin ORCID, B. de Bruin, Alan E. Rowan, Huub Kooijman, Anthony L. Spek, Roeland J. M. Nolte
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This paper is available in a repository.

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Abstract

Exceptionally high binding constants Ka of up to 57000 have been determined for the binding of paraquat and polymeric paraquat derivatives 2 in the cavities of basket-shaped host molecules 1. Host–guest complexations of this kind are of interest with respect to the modification of the physical properties of electroactive polymers, which are potential molecular switches.