Thieme Gruppe, Synthesis: Journal of Synthetic Organic Chemistry, 04(1995), p. 449-452, 1995
DOI: 10.1055/s-1995-3925
Full text: Download
The Pinner salt 2 derived from alpha-azidoacetonitrile by sequential treatment with triethylamine, triphenylphosphine and acyl chlorides or isothiocyanates was converted into the corresponding imidazole 5 or 6, respectively. The crystal structure of 6a has been determined by X-ray diffraction methods. Dimers of centrosymmetrically related molecules, linked by N-H...N bonds, join together to infinite chains through N-H...S=C halogen interactions.