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Wiley, Angewandte Chemie International Edition, 31(43), p. 4049-4052, 2004

DOI: 10.1002/anie.200453761

Wiley, Angewandte Chemie, 31(116), p. 4141-4144, 2004

DOI: 10.1002/ange.200453761

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Stepwise Construction of Oligomeric 1,2-Diselenolene Platinum(IV) Complexes

Journal article published in 2004 by Xavi Ribas ORCID, João C. Dias, Jorge Morgado, Klaus Wurst, Manuel Almeida, Teodor Parella ORCID, Jaume Veciana ORCID, Concepció Rovira
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Abstract

Surrounded by selenium: Pulse field gradient spin-echo (PGSE) NMR diffusion studies of a mixture of oligomeric 1,2-diselenolene PtIV complexes are performed to characterize the species in solution (see structure: n = O (1), n = 1 (2), n = 2 (3); red Pt, green Se, blue N, gray C). The results are in accord with the single-crystal X-ray diffraction structures obtained for the chiral complexes {PtIVSe6} (1) and {PtIV2Se10} (2).