Published in

Elsevier, Inorganic Chemistry Communications, 1(11), p. 117-120

DOI: 10.1016/j.inoche.2007.10.018

Links

Tools

Export citation

Search in Google Scholar

Novel nickel(II) complex bearing phthalimido ligands derived from oxime-mediated transformation of phthalonitrile

Journal article published in 2008 by Maximilian N. Kopylovich, Matti Haukka, Alexander M. Kirillov ORCID, Vadim Y.-U. Kukushkin ORCID, Armando J. L. Pombeiro
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The new heteroligand phthalimido-ethylenediamine nickel(II) complex [Ni{trans-(pti)2}(en)2] (2) has been prepared via the oxime-mediated transformation of phthalonitrile to the phthalimido (or phthalimidato) (pti) moiety in the presence of Ni(NO3)2·6H2O, 2-propanone oxime and ethylenediamine (en). Compound 2 has been characterized by IR, FAB+-MS and 1H NMR spectroscopy, elemental and single crystal X-ray diffraction analyses, showing a slightly distorted octahedral geometry around the centrosymmetric Ni centre with trans phthalimido ligands and ethylenediamine moieties in the equatorial sites.