American Chemical Society, Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 8(108), p. 2568-2574, 2004
DOI: 10.1021/jp036260v
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In this paper we study and rationalize the formation of neutral copper clusters from dimer to nonamer using the available experimental data of binding energies and electronic properties. A complete and consistent picture of the formation of copper clusters in terms of the changes in chemical potential and hardness emerges indicating that the one-atom growth reactions are mainly driven by changes in hardness. An analytic expression for the binding energy as a function of the cluster size is proposed and used to predict the growth pattern of copper clusters.