Published in

American Institute of Physics, The Journal of Chemical Physics, 4(139), p. 044503

DOI: 10.1063/1.4813071

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Ultrafast dynamics of liquid water: Frequency fluctuations of the OH stretch and the HOH bend

Journal article published in 2013 by Sho Imoto, Sotiris S. Xantheas ORCID, Shinji Saito
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Frequency fluctuations of the OH stretch and the HOH bend in liquid water are reported from the third-order response function evaluated using the TTM3-F potential for water. The simulated two-dimensional infrared spectra of the OH stretch are similar to previously reported theoretical results. The present study suggests that the frequency fluctuation of the HOH bend is faster than that of the OH stretch. The ultrafast loss of the frequency correlation of the HOH bend is due to the strong couplings with the OH stretch as well as the intermolecular hydrogen bond bend.