Springer, Journal of Materials Research, 3(30), p. 407-416, 2014
DOI: 10.1557/jmr.2014.317
Full text: Unavailable
Electrochemical reactions at both positive and negative electrodes in a nickel metal hydride (Ni-MH) battery during charge have been investigated by in situ neutron powder diffraction. Commercially available b-Ni(OH) 2 and LaNi 5 -based powders were used in this experiment as positive and negative electrodes, respectively. Exchange of hydrogen by deuterium for the b-Ni(OH) 2 electrode was achieved by ex situ cycling of the cell prior to in situ measurements. Neutron diffraction data collected in situ show that the largest amount of deuterium contained at the positive electrode is de-intercalated from the electrode with no phase transformation involved up to ;100 mA h/g and, in addition, the 110 peak width for the positive electrode increases on charge. The negative electrode of composition MmNi 3.6 Al 0.4 Mn 0.3 Co 0.7 , where Mm 5 Mischmetal, exhibits a phase transformation to an intermediate hydride c phase first and then to the b phase on charge. Unit cell dimensions and phase fractions have been investigated by Rietveld refinement of the crystal structure.