This study examined the degree of independence between Positive Affect (PA) and Negative Affect (NA) within a given situation. The affective state was measured before and after an experimentally induced success or failure experience in an anagram task. Two types of affect measures were used to assess PA and NA: the Positive and Negative Affect Schedule (PANAS) and a Pleasantness-Unpleasantness scale. Consistent with our hypotheses, results show that PA and NA are independent when measured with the PANAS but are correlated when assessed with the other scale. These PA-NA correlations differed significantly from each other before and after emotion induction, respectively. Additional analyses indicate that both PA scales are differentially sensitive to the mood induction procedure. The findings are discussed with respect to circumplex models of emotion.