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Wiley, Angewandte Chemie International Edition, 12(51), p. 2960-2963, 2012
Wiley, Angewandte Chemie, 12(124), p. 3014-3017, 2012
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Carbon-Centered Radicals Can Transfer Hydrogen Atoms between Amino Acid Side Chains
Journal article published in 2012 by
Quentin Raffy,
David-Alexandre Buisson,
Jean-Christophe Cintrat,
Bernard Rousseau,
Serge Pin,
Jean Philippe Renault 
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Abstract
Radical migration between aliphatic amino acid side chains can occur in solution and intramolecularly in peptides. The kinetic constant of the hydrogen transfer reaction was measured by using competition kinetics, and the half-life as well as the distance that a radical can move within a protein was calculated.