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Elsevier, Inorganic Chemistry Communications, 1(14), p. 235-237

DOI: 10.1016/j.inoche.2010.11.001

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Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds

Journal article published in 2011 by Xia Chen, Xiaoyan Xue, Liping Zhang, Wen-Hua Sun ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The reaction of 9-trimethylsilylfluorenyllithium (C13H8SiMe3)Li (1) with α-hydrogen-free nitriles gave highly sensitive lithium compounds, (η3-C13H8SiMe3)Li(tBuCN)(Et2O) (2), [η3-(C13H8)C(NMe2)N(SiMe3)]Li (Et2O)2 (3) and [η3,η6-(C13H8)C(Ph)N(SiMe3)Li]2 (4), illustrating bonding features of η3-allyl, η3-azaallyl, and η6-arene interactions.