Published in

Wiley, Angewandte Chemie International Edition, 9(51), p. 2142-2145, 2012

DOI: 10.1002/anie.201107116

Wiley, Angewandte Chemie, 9(124), p. 2184-2187, 2012

DOI: 10.1002/ange.201107116

Links

Tools

Export citation

Search in Google Scholar

Crystallographic Evidence for Reversible Symmetry Breaking in a Spin-Crossover d7 Cobalt(II) Coordination Polymer

Journal article published in 2012 by Kishalay Bhar, Sumitava Khan, José Sánchez Costa, Joan Ribas, Olivier Roubeau ORCID, Partha Mitra, Barindra Kumar Ghosh
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

All in a spin: A cobalt(II) coordination polymer has a highly cooperative spin-crossover (SCO) behavior with a small hysteresis loop (see picture; HS=high spin, LS=low spin). The correlation of the magnetic properties with the crystal structures was determined at different temperatures. This study reveals an unprecedented reversible symmetry breaking in a d(7) SCO coordination polymer.