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IOP Publishing, Journal of Physics: Condensed Matter, 22(22), p. 225902, 2010

DOI: 10.1088/0953-8984/22/22/225902

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Spectroscopy of f–f radiative transitions of Y b3 +ions in ytterbium doped orthophosphates at ambient and high hydrostatic pressures

Journal article published in 2010 by A. Kaminska ORCID, A. Duzynska, A. Suchocki, M. Bettinelli
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Studies of absorption and luminescence spectra, and luminescence decay times of the intrashell f-f transitions of Y b(³+) ions in bulk orthophosphates at different temperatures and at high hydrostatic pressures are presented. The spectroscopic properties of Y₀.₉₉Y b₀.₀₁PO₄ crystal with a tetragonal zircon structure and Gd₀.₉₉Y b₀.₀₁PO₄ and La₀.₉₅Y b₀.₀₅PO₄ crystals with a monoclinic monazite structure are compared. Experiments at ambient pressure were performed at temperatures from 10 to 295 K whereas measurements at high pressure were performed in a diamond-anvil cell at 10 K with a pressure up to 160 kbar. The results reveal a high thermal and pressure stability of the optical properties of the examined crystals as well as the dependence of Y b(³+) emission properties on the local symmetry of the site occupied by the ytterbium dopant.