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Sociedade Brasileira de Química, SBQ, Journal of the Brazilian Chemical Society, 5(12), p. 673-679, 2001

DOI: 10.1590/s0103-50532001000500011

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A New Approach to the Synthesis of (±)-Methyl Jasmonate and (±)-Baclofen via Conjugated Addition of Oxazoline Cyanocuprate to Michael Acceptors

Journal article published in 2001 by Santos Alcindo A. Dos, Alcindo A. dos Santos, C. Clososki Giuliano ORCID, Fabio Simonelli, Oliveira Alfredo R. M. De ORCID, Alfredo R. M. de Oliveira, A. Marques Francisco de, H. G. Zarbin Paulo
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Introduction of a synthon equivalent to a carboxymethyl anion to enones and nitroalkenes, through a 1,4-addition reaction of 2,4,4-trimethyl-2-oxazoline cyanocuprate 3, proved to be an interesting methodology for the synthesis of natural products such as (±)-methyl jasmonate (1) and (±)-baclofen (2).