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American Chemical Society, Langmuir, 8(10), p. 2736-2742, 1994

DOI: 10.1021/la00020a039

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Effect of Dissolved Gas and Salt on the Hydrophobic Force between Polypropylene Surfaces

Journal article published in 1994 by Laurence Meagher ORCID, Vincent S. J. Craig ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The hydrophobic interaction between polypropylene surfaces in NaCl solutions has been measured using a modified atomic force microscope (AFM). An attractive force of 30 nm range was measured. This is of much shorter range than that reported for Langmuir-Blodgett deposited surfactant films on mica. Removal of the gases dissolved in dilute NaCl solutions was found to reduce the range of the interaction. Increased NaCl concentration up to 1 M has little or no effect on the range of the interaction, within experimental error. The results have implications for the mechanism of the long range hydrophobic interaction.