Published in

American Chemical Society, Journal of the American Chemical Society, 49(132), p. 17447-17451, 2010

DOI: 10.1021/ja104189p

Wiley-VCH Verlag, ChemInform, 13(42), p. no-no, 2011

DOI: 10.1002/chin.201113007

Links

Tools

Export citation

Search in Google Scholar

ChemInform Abstract: Structure-Induced Ferromagnetic Stabilization in Free-Standing Hexagonal Fe1.3Ge Nanowires.

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Red circle
Preprint: archiving forbidden
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Single-crystalline free-standing hexagonal Fe(1.3)Ge nanowires (NWs) are synthesized for the first time using a chemical vapor transport process without using any catalyst. Interestingly, Fe(1.3)Ge NWs are found to be ferromagnetic at room temperature, while bulk Fe(1.3)Ge has the lower critical temperature of 200 K. We perform first-principles density functional calculations and suggest that the observed strong ferromagnetism is attributed to the reduced distances between Fe atoms, increased number of Fe-Fe bonds, and the enhanced Fe magnetic moments. Both experimental and theoretical studies show that the magnetic moments are enhanced in the NWs, as compared to bulk Fe(1.3)Ge. We also modulate the composition ratio of as-grown iron germanide NWs by adjusting experimental conditions. It is shown that uniaxial strain on the hexagonal plane also enhances the ferromagnetic stability.