The synthesis of new bipyrazole derivatives (1, 3, 4) is reported. The structures of these products were confirmed by IR, MS, EA and NMR (1 H and 13 C) spectroscopy. The extraction behaviour of Cu (II), Cd (II) and Pb (II) from aqueous solution has been investigated with dichloromethane solution for compounds (1-4). The percentage of the extracted cation was determined by atomic absorption spectroscopy measurements.