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American Chemical Society, Journal of the American Chemical Society, 13(134), p. 5742-5745, 2012

DOI: 10.1021/ja3004792

Wiley-VCH Verlag, ChemInform, 37(43), p. no-no, 2012

DOI: 10.1002/chin.201237181

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C(sp)–C(sp3) Bond Formation through Cu-Catalyzed Cross-Coupling ofN-Tosylhydrazones and Trialkylsilylethynes

Journal article published in 2012 by Fei Ye, Xiaoshen Ma ORCID, Qing Xiao, Huan Li, Yan Zhang, Jianbo Wang
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Copper-catalyzed cross-coupling of N-tosylhydrazones with trialkylsilylethynes leads to the formation of C(sp)-C(sp(3)) bonds. Cu carbene migratory insertion is proposed to play the key role in this transformation.