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Wiley, Angewandte Chemie International Edition, 6(49), p. 1075-1078, 2010

DOI: 10.1002/anie.200905497

Wiley, Angewandte Chemie, 6(122), p. 1093-1096, 2010

DOI: 10.1002/ange.200905497

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Hierarchical self-assembly of a chiral metal-organic framework displaying pronounced porosity

Journal article published in 2010 by Jack K. Clegg, Simon S. Iremonger, Michael J. Hayter, Peter D. Southon, Rene B. Macquart, Martin B. Duriska, Paul Jensen, Peter Turner, Katrina A. Jolliffe ORCID, Cameron J. Kepert, George V. Meehan, Leonard F. Lindoy
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Abstract

Into the void: A large, cavity-containing trinuclear triangle with accessible binding sites has been synthesized, structurally characterized, and incorporated into a chiral metal-organic framework (see picture). The resulting 3D framework, with a afunctional amine bridging group, has a void volume of 56% that is accessible to solvent and adsorbs a variety of gases to various degrees. (Figure Presented)