A tristable [2]catenane, composed of a macrocyclic polyether incorporating 1,5-dioxynaphthalene (DNP) and tetrathia-fulvalene (TTF) units, along with a 4,4'-bipyridinium (BIPY?+) radical cation as three very different potential recognition sites, interlocked mechanically with the tetracationic cyclophane, cyclobis(paraquat-p-phenylene) (CBPQT4+), was synthesized by donor-acceptor templation, employing a ?threading-followed-by-cyclization? approach. In this catenane, the movement of the CBPQT4+ ring in its different redox states between these three potential recognition sites, and the corresponding color changes, are achieved by tuning external redox potentials. In the starting state, where no external potential is applied, the ring encircles the TTF unit, displaying a green color. Upon oxidation of the TTF unit, the CBPQT4+ ring moves to the DNP unit, producing a red color. Finally, if all the BIPY2+ units are reduced to BIPY?+ radical cations, the resulting CBPQT2(?+) diradical dication will migrate to the BIPY?+ unit, resulting in a purple color. These readily switchable electrochromic properties render the [2]catenane attractive for use in electro-optical devices.