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Sociedade Brasileira de Química, SBQ, Journal of the Brazilian Chemical Society, 2015

DOI: 10.5935/0103-5053.20150293

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Use of Natural Rubber Membranes as Support for Powder TiO<sub>2</sub>and Ag/TiO<sub>2</sub>Photocatalysts

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The purpose of this study was to synthesize TiO 2-polymer composites able to act as photocatalyst membranes. TiO 2 catalysts were prepared using the sol-gel method to contain 0.0, 0.5, 1.0, and 2.0 wt.% of embedded Ag particles, subsequently incorporated into natural rubber latex at a weight fraction of 15%. Samples of these ceramic powders were suspended in a latex emulsion (natural rubber), cast in Petri dishes and slowly dried in an oven. The resulting materials were evaluated by X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray, diffuse reflectance spectroscopy, differential scanning calorimetry, thermogravimetry, and photocatalytic assaying using methylene blue as an organic pollutant reference. All composite membranes exhibited good photoactivity conferred by TiO 2 powder, with 98% dye fading after 300 min of ultraviolet irradiation.