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Instytut Podstaw Informatyki, Acta Physica Polonica A, 10(115), p. 263-265, 2009

DOI: 10.12693/aphyspola.115.263

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Defect-Related Origin of the Ferromagnetism in ZnO:Co

Journal article published in 2009 by R. Hanafin, C. D. Pemmaraju, T. Archer ORCID, S. Sanvito
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In recent years transition metal ion doped ZnO has been the focus of intense scientific enquiry. ZnO:Co is by far the most studied member of this family. However, despite the many experimental claims for ferromagnetism, a definitive theoretical explanation for long range magnetic interaction has so far been lacking. Here we present a mechanism which describes not only the origin of this previously inexplicable magnetism but also explains the experimental findings to date and in addition, suggests a recipe for tailoring the magnetic properties. We demonstrate that the magnetism originates from a Co 2+ oxygen vacancy pair with a partially filled level close to the ZnO conduction band minimum. The long range coupling then occurs via conduction electrons at moderate n doping. This however is not sufficient for room temperature ferromagnetism due to the prohibitive concentrations of O vacancies needed. The experimental findings may then be explained by a combination of our proposed mechanism and the formation of blocked superparamagnetic clusters.