The aim of this study is to establish different socio-cultural models based on lithic raw material sourcing integrated with regional rock art distributions to infer social behaviours within the context of central Iberian Upper Palaeolithic societies. Specifically, we focus on Upper Palaeolithic hunter–gatherer mobility and social interaction in the Côa Valley. This study relies on a knowledge of regional geology and field work to identify the sources of the lithic raw material found at Côa Valley Upper Palaeolithic sites. We expose the context of use and discard of flint, which is naturally absent from the region, and other local materials. From this, we present a GIS based analysis concerning space, time and least-cost paths travelled. This analysis, along with the environmental data available, forms a baseline to evaluate different anthropological models on hunter–gatherer lithic use, mobility, and social networks. We conclude with a three-level model for social interaction, in the context of aggregation activities between different social meta-groups, which involves embedded procurement, long-distance raw material exchange, and symbolic community, reflected in the largest known open-air Upper Palaeolithic rock art concentration.