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Wiley, Journal of Inorganic and General Chemistry, 8(636), p. 1549-1556, 2010

DOI: 10.1002/zaac.200900540

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Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)

Journal article published in 2010 by Aleksandra Wiśniewska, Katarzyna Baranowska, Rafał Grubba ORCID, Eberhard Matern, Jerzy Pikies
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

tBu(2)P-PLi-PtBu2 center dot 2THF reacts with [(R3P)(2)MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol(3)P, Ph2EtP, iPr(3)P) to yield isomers of [(1,2-eta-tBu(2)P=P-PtBu2)M(PR3)Cl], in which the tBu(2)P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butyl-phosphanyl)diphosphenium cation. tBu(2)P-PLi-P(NEt2)(2)center dot 2THE reacts with [(R3P)(2)MCl2] but does not form complexes with a tBu(2)P-P-P(NEt2)(2) moiety, however, splitting of a P P(NEt2)2 bond of the parent triphosphane takes place.