The performance of daily and hourly diffuse horizontal solar irradiation models and correlations is examined using an assembled data set of multivariate meteorological time series from countries in the North Mediterranean Belt area. The correlations reviewed use only daily global, hourly global or daily diffuse irradiation as input, for the daily or hourly time scale. The best overall performance was presented by the Frutos correlation for the estimation of the daily diffuse radiation by an adapted version of the Liu and Jordan correlation for the mean daily diffuse radiation profile, and by the Hollands and Crha model for estimation of hourly diffuse values from the corresponding global values. The results show that the best correlation for each site varies. Two empirical piecewise correlations were also developed by the authors with the help of the data bank available, yielding models that showed even better fits to the data. The results show some seasonal and location dependence.