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American Chemical Society, Journal of the American Chemical Society, 10(126), p. 3014-3015, 2004

DOI: 10.1021/ja039472e

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Mineralomimetic Sodalite- and Muscovite-Type Coordination Frameworks. Dynamic Crystal-to-Crystal Interconversion Processes Sensitive to Ion Pair Recognition

Journal article published in 2004 by Elisa Barea, Jorge A. R. Navarro ORCID, Juan M. Salas, Norberto Masciocchi ORCID, Simona Galli, Angelo Sironi
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A flexible sodalite-type metal organic framework [Cu(pyrimidine-2-olate)2]n (1R) is obtained in a self-assembly process involving Cu2+ ions and pyrimidine-2-olate ligands. 1R suffers a series of sequential and reversible structural changes upon solid-liquid sorption processes of metal nitrates. The 1C-to-1O transformation occurs only with large cations.