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American Chemical Society, Organometallics, 19(27), p. 5108-5117, 2008

DOI: 10.1021/om8006807

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Unexpected Structure of Palladacycles Containing Carboxylated Schiff Bases. Synthesis of Some Water-Soluble Metallacycles

This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The action of palladium acetate on carboxylated Schiff bases is herein described. These reactions lead to new metallacycles, some of which are hydrosoluble. Additionally we present the first report of cyclopalladated derivatives having the metalated molecule as a dianionic (C,N,O) bridging ligand between two palladium atoms.