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Elsevier, Marine Chemistry, 1(12), p. 69-85

DOI: 10.1016/0304-4203(83)90029-4

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The Reproducibility in the Determination of Heavy-Metals in Marine Plant-Material - an Interlaboratory Calibration

Journal article published in 1983 by Hans Brix ORCID, Jens Erik Lyngby, Hans-Henrik Schierup
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Results from an interlaboratory calibration exercise on the reproducibility in the determination of cadmium, chromium, copper, iron, manganese, nickel, lead, and zinc in marine plant material are presented. The fourteen participating laboratories each analysed the heavy metal content in two samples of dried eelgrass material (spiked and unspiked), a predigested sample, and a mixed standard solution.Significant variations in the reported heavy metal concentrations were observed. The variability between laboratories was greatest for cadmium, chromium, nickel, and lead, whereas the variability for iron, manganese, and zinc was less. The reproducibility in reported heavy metal concentrations was generally best in the mixed standard solution and poorest in the dried eelgrass samples. Statistical analyses showed that some laboratories generally reported values closer to the overall means than did others.The sources of variation are discussed, and recommendations to improve the quality of heavy metal analyses are given.