Published in

Elsevier, Journal of Organometallic Chemistry, 1-2(379), p. 177-185

DOI: 10.1016/0022-328x(89)80037-3

Links

Tools

Export citation

Search in Google Scholar

Insertions of diphenylacetylene into cyclopalladated compounds. Crystal structure of [PdNCH(2,6-C6H3Cl2)}Br]

Journal article published in 1989 by Joan Albert, Jaume Granell ORCID, Joaquim Sales, Xavier Solans
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The reaction between [Pd{C6H4CH2N=CH(2,6-C6H3Cl2)}Br]2 and PhCCPh gives the bis-insertion compound [Pd{(PhC=CPh)2C6H4CH2N=CH(2,6-C6H3Cl2} Br] in good yield. This compound crystallizes in the monoclinic space group P21/a, with a 18.757(3), b 15.678(3), c, 12.150(2) Å β 92.83(2)° and Z = 4; R = 0.063 for 2076 reflections. The palladium atom is coordinated to Br, N, C(18), and the centre of the C(15)–C(16) double bond in a distorted square-planar geometry.