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Elsevier, Chemical Physics Letters, 3-4(235), p. 260-267

DOI: 10.1016/0009-2614(95)00122-k

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Solvation effects and short-time photodissociation dynamics of CH2I2 in solution from resonance Raman spectroscopy

Journal article published in 1995 by Wai Ming Kwok ORCID, David Lee Phillips, Wai Ming Kwok, David Lee Phillips
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Resonance Raman spectra of CH2I2 in cyclohexane solution have been obtained within the directly dissociative A-state absorption band of CH2I2 at excitation wavelengths of 355 and 341.5 nm. We find several intense vibrational bands in the solution phase spectra that are not observed in a previously reported 355 nm gas phase spectrum indicating that solvation effects are important in the Franck-Condon region of the first electronic excited state of CH2I2. The solution phase short-time photodissociation dynamics appears to have more motion in the ICI bending coordinate than the gas phase photodissociation.