Published in

American Chemical Society, Crystal Growth and Design, 1(6), p. 94-98, 2005

DOI: 10.1021/cg050186j

Links

Tools

Export citation

Search in Google Scholar

Synthesis, Crystal Structure, and Magnetic Properties of a Three-Dimensional Cyano-Bridged Bimetallic Coordination Polymer with an Aromatic Amine Capping Ligand:  [Cu(2,2‘-dpa)]3[Cr(CN)6]2·3H2O (2,2‘-dpa = 2,2‘-Dipicolylamine)

Journal article published in 2006 by Cai-Ming Liu ORCID, Song Gao, Hui-Zhong Kou, De-Qing Zhang, Hao-Ling Sun, Dao-Ben Zhu
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

A three-dimensional (3D) Cu(II)-containing Prussian Blue analogue with two types of [Cr(CN)6]3- units, [Cu(2,2‘-dpa)]3[Cr(CN)6]2·3H2O (2,2‘-dpa = 2,2‘-dipicolylamine), was synthesized and characterized. One type of [Cr(CN)6]3- unit in this complex coordinates to six copper(II) atoms to form the heptanuclear [CrCu6] unit, which connects with other [CrCu6] units through the other type of [Cr(CN)6]3- unit acting as bidentate spacer link only. Magnetic investigations of this complex revealed that long-range ferromagnetic ordering occurs below the Curie temperature of 3 K. It is the first example of 3D complex-based Prussian Blue analogues containing aromatic amine capping ligands.