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American Institute of Physics, Applied Physics Letters, 23(96), p. 231906

DOI: 10.1063/1.3447798

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Reduction of the Transverse Effective Charge of Optical Phonons in ZnO Under Pressure

This paper is available in a repository.
This paper is available in a repository.

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Abstract

From Raman scattering on a-plane wurtzite ZnO crystals we obtained a decreasing splitting between longitudinal and transversal optical phonons with A1 and E1 symmetry as a function of hydrostatic pressure up to 5.5 GPa. Consequently, the transverse effective charge e T exhibits a strong reduction with increasing pressure, yielding 2.17–14.6x10E−3 P/GPa and 2.04–13.7x10E−3 P/GPa in units of the elementary charge for the A1 and E1 phonons, respectively. We find a clear systematic in the linear pressure coefficient of eT* with bond polarity for the series of wide-band gap semiconductors SiC, AlN, GaN, and ZnO.