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Elsevier, Fluid Phase Equilibria, 1-2(294), p. 157-179

DOI: 10.1016/j.fluid.2010.03.010

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Studies on the density, heat capacity, surface tension and infinite dilution diffusion with the ionic liquids [C(4)mim][NTf(2)], [C(4)mim][dca], [C(2)mim][EtOSO(3)] and [Aliquat][dca]

Journal article published in 2010 by Carlos A. Nieto de Castro, Elisa Langa, Ana L. Morais, Manuel L. Matos Lopes, Manuel L. Matos Lopes, Maria J. V. Lourenco, Fernando J. V. Santos, Soledade M. C. S. Santos, M. Soledade C. S. Santos, José N. Canongia Lopes, José N. Canongia Lopes ORCID, Helena I. M. Veiga, Mafalda Macatrao, Jose M. S. S. Esperanca ORCID, Carolina S. Marques and other authors.
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Abstract

Ionic liquids are a class of fluids that requires the attentions of experimentalist and theoreticians. In a new project on synthesis and characterization of new and not-so-new ionic liquids, the study of several thermophysical properties of these liquids was started, namely binary diffusion, electrical conductivity, heat capacity, surface tension, viscosity and thermal conductivity. Among others we will study 1-n-butyl-3-methyl-imidazolium bis(trifluoromethanesulfonyl)imide, ([C4mim][NTf2]), 1-n-butyl-3-methyl-imidazolium dicyanamide, ([C4mim][dca]), 1-ethyl-3-methyl-imidazolium ethylsulfate, ([C2mim][EtOSO3]) and methyltrialkylammonium dicyanamide [Aliquat®336-derived][dca], and in the case of diffusion, their mixtures with water.